|
The first
question which surfaces once we are thinking about distilling alcohol is:
will my home made Booze be safe
or will I go Blind???
In many articles in the press and sometimes even on the news, we are
informed that distilling alcohol in a non-correct way will case serious
health problems like turning blind or even fatal liver damage which might
cause your life.....
In general, we
are speaking about "alcohol". We need to precise this term as
there are several different materials during fermentation. Luckily for us,
these different alcohols have a different boiling point, which allows us
te seperated teh various components into toxic and non-toxic components.
Ethanol
versus Methanol - what is what....?
-
Ethanol
is the alcohol which we are aiming for. This will not
cause any health issues if consumed in a sensible quantity.
-
Methanol
(methyl alcohol, wood alcohol) is the alcohol which is the one which is
toxic and should therefor not be consumed. Methanol is the simplest
alcohol, containing one carbon atom. It is a colorless, tasteless
liquid with a very faint odor and is commonly known as "wood
alcohol." A few teaspoons of 100% pure methanol can cause
blindness and a few tablespoons can be fatal, if the exposure is not
treated.
It should be
noted that the human body can metabolize and eliminate low concentrations
of methanol with no ill effects. (Methanol is present in many cooked
vegetables, and the artificial sweetener in diet soft drinks breaks down
into methanol during digestion.) Methanol becomes poisonous only when it
overwhelms the body's capacity to remove it. Toxic effects do not occur
until several hours after exposure. Effective antidotes to methanol
poisoning are readily available and can be administered during this
interim period.
Methanol is
formed by.....
-
Methanol
is formed when fermenting beverages high in pectins.
Pectin (E440)
is a structural polysaccharide, found in fruit and vegetables and
mainly prepared from citrus peel. In the food industry, Pectins are
mainly used as gelling agents, but can also act as thickener, water
binder and stabilizer.
PECTIN RICH
FRUITS are: apples, plums, grapes, berries etc.
Distillation,
seperating the methanol from the ethanol
During distillation,
we are seperating the various components of our wash, based on different
boiling points. The boiling points which can be identified are:

To
conclude: the hazardous material report on Methanol
|
Flashpoint
|
54 degrees F
|
IDLH (Immediately Dangerous to Life and Health)
|
25,000 ppm
|
|
Ignition Temperature
|
725 degrees F
|
TLV/TWA (Threshold Limit Value/Time Weighted Average)
|
200 ppm
|
|
LEL (Lower Exposure Limit)
|
6%
|
STEL (Short Term Exposure Limit)
|
250 ppm
|
|
UEL (Upper Exposure Limit)
|
36.5%
|
|
|
“Moonshiners” have used methyl alcohol for years because of its similarity in
taste to ethyl alcohol and increase in alcohol volume. There are several
industrial uses for methanol such as in the manufacture of plastics, soaps, inks
and cleaning products, as well as a solvent for many materials.
Methanol is a clear, colorless liquid with the sweet and pungent odor of
alcohol. It is also completely soluble and non-reactive in water.
The boiling point of methanol is 148.1degrees F and its freezing point is -144
degrees F. The odor of methanol can be detected at 100ppm.
Some general hazards of methanol are that it will react with strong
oxidizers, chloroform and strong corrosives such as sulfuric acid, sodium
hydroxide, and potassium hydroxide. It is also flammable and produces
vapors that, if allowed to accumulate, could produce an explosion when
ignited. Methanol also burns somewhat “cleanly” which means it gives a
pale blue flame that can be difficult to see in bright sun-light.
There are many health hazards associated with methanol whether through
ingestion, inhalation, or skin contact. Methyl alcohol is a chemical
poison that interrupts vital nerve impulses through attacking the optic nerve
and possibly causing blindness, if not death. Consumption of a 1/4 oz. or
more may be fatal. At high air concentrations (50,000 ppm) for an hour or
longer, methanol will cause optic nerve damage, central nervous system
depression, or death. Ingestion is the most common form of
methanol poisoning. If ingestion does occur and the victim is conscious,
administer a concentrated solution of salt water, and induce vomiting only if
medical attention isn’t immediately available. If the victim is
unconscious, keep the person warm and seek medical attention immediately.
Methyl alcohol also has distinct narcotic properties.
Inhalation of high vapor concentrations can produce drunkenness, drowsiness,
light-headedness, blurred vision, blindness, unconsciousness and death. In
some cases, the effects may be delayed 24 hours or longer. If enough
methyl alcohol vapors have been inhaled to produce symptoms of intoxication
remove the person to fresh air immediately and keep the person calm and
warm. Artificial respiration must be administered if breathing has become
difficult or stopped. Contact of the liquid with the skin and
eyes should be avoided. Repeated contact with the liquid will cause
defatting of the skin and irritation of the skin and eyes. If skin contact
has occurred, remove contaminated clothing and wash affected areas of the body
with large amounts of water. In the case of eye contact, eyes should be
flushed with water for at least 15 minutes, lifting the lids occasionally.
The best protection against eye and skin contact to methyl alcohol is the use
of splash-proof goggles and gloves.
|